Modified Van der Waals equation and law of corresponding states
نویسندگان
چکیده
منابع مشابه
Generalized van der Waals equation of state*
The quantitative thermodynamic effect of adding a weak, long-range attraction to inverse-power repUlsive potentials is studied. The resulting phase diagrams exhibit two fluid phases and a solid phase. a critical point, a triple point, and, for sufficiently soft repulsions, an additional solid phase with an additional triple point. The effects of attractions other than van der Waals' are studied...
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The thermodynamic properties, enthalpy of vaporization, entropy, Helmholtz function, Gibbs function, but especially the heat capacity at constant volume of a van der Waals gas (and liquid) at the phase transition are examined in two different limit approximations. The first limit approximation is at the near-critical temperatures, i.e., for T/Tc → 1, where Tc is the critical temperature, the ot...
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A modified two-dimensional van der Waals equation model was proposed for the prediction of multicomponent gas-solid adsorption isotherms from corresponding single-component adsorption equilibrium data. The model was used to predict adsorption isotherms of CO-CO2 mixtures and CO2-N2 mixtures on Cu(I)-NaY zeolite. Experimental adsorption equilibrium data of the two systems were compared with resu...
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ژورنال
عنوان ژورنال: Physica A: Statistical Mechanics and its Applications
سال: 2017
ISSN: 0378-4371
DOI: 10.1016/j.physa.2016.12.029